Correlative microscopy of single self-assembled nanorod dimers for refractometric sensing
نویسندگان
چکیده
Single metallic particles and dimers of nanospheres have been used extensively for sensing, but provide attractive advantages because they exhibit multiple modes that can be tuned by the dimer geometry. Here, we employ correlative microscopy single self-assembled gold nanorods to study their performance as refractometric sensors. The correlation between atomic force single-particle white-light spectroscopy allows us relate measured sensitivity numerical simulations taking into account exact geometry construct. antibonding mode is in good agreement with simulations, whereas bonding exhibits a reduced related accessibility gap region particles. We find figure merit trade-off resonance linewidth its refractive index sensitivity, which depend opposite ways on interparticle angle. presence two narrow plasmon resonances visible near-infrared wavelength regime makes nanorod exciting candidates multicolor multiplexed sensing.
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ژورنال
عنوان ژورنال: Journal of Chemical Physics
سال: 2021
ISSN: ['1520-9032', '1089-7690', '0021-9606']
DOI: https://doi.org/10.1063/5.0055135